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http://hdl.handle.net/20.500.12323/8169| Title: | Synthesis and structure of 6-bromo-2-(diethoxymethyl)- 2-hydroxy-3-phenyl-2,3-dihydro-1Himidazo[ 1,2-a]pyridin-4-ium chloride acetonitrile monosolvate |
| Authors: | Guseinov, Firudin I. Samigullina, Aida I. Hökelek, Tuncer Hamidov, Sahil Z. Lasri, Jamal Hasanov, Khudayar I. Javadzade, Tahir A. Belay, Alebel N. |
| Keywords: | crystal structure non-covalent interactions hydrogen bond imidazole |
| Issue Date: | Jul-2025 |
| Publisher: | International Union of Crystallography |
| Series/Report no.: | Vol. 81;Acta Crystallographica Section E, Crystallographic Communications, № 8 |
| Abstract: | In the title solvated molecular salt, C18H22BrN2O3+·Cl−·CH3CN, the imidazole ring is in envelope conformation and the pyridine and phenyl rings are oriented at a dihedral angle of 72.52 (5)°. In the crystal, O—H⋯Cl and N—H⋯Cl hydrogen bonds link the cations and anions into centrosymmetric tetramers enclosing R24(12) loops. Short Br⋯Cl [3.2313 (4) Å] and O⋯Cl [3.0490 (10) Å] contacts are observed. A Hirshfeld surface analysis of the structure indicates that the most important contributions for the crystal packing are from H⋯H (52.4%), H⋯C/C⋯H (12.1%), H⋯Br/Br⋯H (11.0%) and H⋯Cl/Cl⋯H (10.2%) interactions |
| URI: | http://hdl.handle.net/20.500.12323/8169 |
| ISSN: | 2056-9890 |
| Appears in Collections: | Publications |
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